Trityl Chloride

CAS# 76-83-5

Trityl Chloride

Catalog No. BCC2805----Order now to get a substantial discount!

Product Name & Size Price Stock
Trityl Chloride:100g $63.00 In stock
Trityl Chloride:200g $107.00 In stock
Trityl Chloride:500g $252.00 In stock
Trityl Chloride:1000g $441.00 In stock
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Quality Control of Trityl Chloride

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Chemical structure

Trityl Chloride

3D structure

Chemical Properties of Trityl Chloride

Cas No. 76-83-5 SDF Download SDF
PubChem ID 6456 Appearance Powder
Formula C19H15Cl M.Wt 278.78
Type of Compound N/A Storage Desiccate at -20°C
Solubility Soluble in water or 1% acetic acid
Chemical Name [chloro(diphenyl)methyl]benzene
SMILES C1=CC=C(C=C1)C(C2=CC=CC=C2)(C3=CC=CC=C3)Cl
Standard InChIKey JBWKIWSBJXDJDT-UHFFFAOYSA-N
Standard InChI InChI=1S/C19H15Cl/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Trityl Chloride Dilution Calculator

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Trityl Chloride Molarity Calculator

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Preparing Stock Solutions of Trityl Chloride

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 3.5871 mL 17.9353 mL 35.8706 mL 71.7412 mL 89.6764 mL
5 mM 0.7174 mL 3.5871 mL 7.1741 mL 14.3482 mL 17.9353 mL
10 mM 0.3587 mL 1.7935 mL 3.5871 mL 7.1741 mL 8.9676 mL
50 mM 0.0717 mL 0.3587 mL 0.7174 mL 1.4348 mL 1.7935 mL
100 mM 0.0359 mL 0.1794 mL 0.3587 mL 0.7174 mL 0.8968 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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Trityl Chloride

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References on Trityl Chloride

Cascade reaction of beta,gamma-unsaturated alpha-ketoesters with phenols in trityl chloride/TFA system. Highly selective synthesis of 4-aryl-2H-chromenes and their applications.[Pubmed:21387069]

Org Biomol Chem. 2011 Apr 21;9(8):2868-77.

The treatment of beta,gamma-unsaturated alpha-ketoesters with phenols in the presence of Trityl Chloride and 4 A molecular sieves in refluxing trifluoroacetic acid afforded 4-aryl-2H-chromenes in high yields, in which a reverse of the regiochemistry of Jorgensen-Rutjes chromane synthesis was observed. The isolation of 4H-chromene intermediates, confirmed by single-crystal X-ray analysis, indicates that the early stage of the reaction involves a Friedel-Crafts alkylation/cyclodehydration processes. Stirring of the 4H-chromene intermediate with Trityl Chloride in deuterotrifluoroacetic acid under reflux afforded the 2H-chromene and triphenylmethane in high yields, which implies the late stage of the reaction involves a hydrogen transfer process. Highly selective derivation of the hydroxyl esters to the corresponding hydroxyl amides, amino acids, amino esters and Friedel-Crafts adducts was further accomplished. Our endeavors will lead to a better understanding of the controlling elements behind their structural motifs. The products were confirmed unambiguously from their spectra and by single-crystal X-ray analysis.

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