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Daphnicyclidin D

CAS# 385384-24-7

Daphnicyclidin D

Catalog No. BCN7081----Order now to get a substantial discount!

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Chemical structure

Daphnicyclidin D

3D structure

Chemical Properties of Daphnicyclidin D

Cas No. 385384-24-7 SDF Download SDF
PubChem ID 10045396 Appearance Powder
Formula C23H27NO4 M.Wt 381.47
Type of Compound Alkaloids Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name methyl (2S,3R,5R,6S,10S)-2,6-dimethyl-21-oxo-14-oxa-8-azahexacyclo[11.6.1.15,19.02,10.03,8.017,20]henicosa-1(19),13(20),17-triene-18-carboxylate
SMILES CC1CN2CC3CCC4=C5C(=C(C6=C5C3(C2CC1C6=O)C)C(=O)OC)CCO4
Standard InChIKey DTNVJGYTJYNCDT-UHCAAFETSA-N
Standard InChI InChI=1S/C23H27NO4/c1-11-9-24-10-12-4-5-15-17-13(6-7-28-15)18(22(26)27-3)19-20(17)23(12,2)16(24)8-14(11)21(19)25/h11-12,14,16H,4-10H2,1-3H3/t11-,12-,14-,16-,23-/m1/s1
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of Daphnicyclidin D

The stems of Daphniphyllum humile and D.teijsmanni.

Biological Activity of Daphnicyclidin D

DescriptionDaphnicyclidin D is a natural product from Daphniphyllum humile and D.teijsmanni.

Protocol of Daphnicyclidin D

Structure Identification
Chem Biodivers. 2006 Nov;3(11):1255-9.

A zwitterionic alkaloid, containing a rare cyclopentadienyl anion unit, from the stem barks of Daphniphyllum macropodum Miq.[Pubmed: 17193239 ]


METHODS AND RESULTS:
A new Daphniphyllum alkaloid daphnicyclidin L (1), containing a rare cyclopentadienyl anion, which is stabilized as a zwitterion by an internal iminium counterion, was isolated from the stem barks of Daphniphyllum macropodum Miq., together with four known alkaloids: Daphnicyclidin D (2), daphnicyclidin H (3), deoxyyuzurimine (4), and yuzurimine (5).
CONCLUSIONS:
The structures were elucidated on the basis of spectroscopic data. The configuration of 1 was elucidated by single-crystal X-ray diffraction crystallography.

Daphnicyclidin D Dilution Calculator

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Daphnicyclidin D Molarity Calculator

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Preparing Stock Solutions of Daphnicyclidin D

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 2.6214 mL 13.1072 mL 26.2144 mL 52.4288 mL 65.536 mL
5 mM 0.5243 mL 2.6214 mL 5.2429 mL 10.4858 mL 13.1072 mL
10 mM 0.2621 mL 1.3107 mL 2.6214 mL 5.2429 mL 6.5536 mL
50 mM 0.0524 mL 0.2621 mL 0.5243 mL 1.0486 mL 1.3107 mL
100 mM 0.0262 mL 0.1311 mL 0.2621 mL 0.5243 mL 0.6554 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on Daphnicyclidin D

A zwitterionic alkaloid, containing a rare cyclopentadienyl anion unit, from the stem barks of Daphniphyllum macropodum Miq.[Pubmed:17193239]

Chem Biodivers. 2006 Nov;3(11):1255-9.

A new Daphniphyllum alkaloid daphnicyclidin L (1), containing a rare cyclopentadienyl anion, which is stabilized as a zwitterion by an internal iminium counterion, was isolated from the stem barks of Daphniphyllum macropodum Miq., together with four known alkaloids: Daphnicyclidin D (2), daphnicyclidin H (3), deoxyyuzurimine (4), and yuzurimine (5). The structures were elucidated on the basis of spectroscopic data. The configuration of 1 was elucidated by single-crystal X-ray diffraction crystallography.

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