PhenothiazineCAS# 92-84-2 |
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Quality Control & MSDS
Number of papers citing our products
Chemical structure
3D structure
| Cas No. | 92-84-2 | SDF | Download SDF |
| PubChem ID | 7108 | Appearance | Powder |
| Formula | C12H9NS | M.Wt | 199.27 |
| Type of Compound | N/A | Storage | Desiccate at -20°C |
| Solubility | Soluble in DMSO > 10 mM | ||
| Chemical Name | 10H-phenothiazine | ||
| SMILES | C1=CC=C2C(=C1)NC3=CC=CC=C3S2 | ||
| Standard InChIKey | WJFKNYWRSNBZNX-UHFFFAOYSA-N | ||
| Standard InChI | InChI=1S/C12H9NS/c1-3-7-11-9(5-1)13-10-6-2-4-8-12(10)14-11/h1-8,13H | ||
| General tips | For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months. We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months. Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it. |
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| About Packaging | 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial. 2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial. 3. Try to avoid loss or contamination during the experiment. |
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| Shipping Condition | Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request. | ||
Phenothiazine Dilution Calculator
Phenothiazine Molarity Calculator
| 1 mg | 5 mg | 10 mg | 20 mg | 25 mg | |
| 1 mM | 5.0183 mL | 25.0916 mL | 50.1832 mL | 100.3663 mL | 125.4579 mL |
| 5 mM | 1.0037 mL | 5.0183 mL | 10.0366 mL | 20.0733 mL | 25.0916 mL |
| 10 mM | 0.5018 mL | 2.5092 mL | 5.0183 mL | 10.0366 mL | 12.5458 mL |
| 50 mM | 0.1004 mL | 0.5018 mL | 1.0037 mL | 2.0073 mL | 2.5092 mL |
| 100 mM | 0.0502 mL | 0.2509 mL | 0.5018 mL | 1.0037 mL | 1.2546 mL |
| * Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations. | |||||
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Phenothiazine is a dopamine-2 (D2) receptor antagonist therefore decreases the effect of dopamine in the brain.
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On how electron density affects the redox stability of phenothiazine sensitizers on semiconducting surfaces.[Pubmed:28154843]
Chem Commun (Camb). 2017 Feb 23;53(17):2547-2550.
The stabilities of three organic dyes that differ only by two substituents (-OMe, -H and -Br) about the Phenothiazine donor unit were evaluated when immobilized on a semiconductor surface. All three dyes delivered modest power conversion efficiencies (PCEs) in the dye-sensitized solar cell (DSSC), but maintained 75% of their initial PCE over 300 h of sustained simulated sunlight. Electron-donating substituents increased the stability of the Phenothiazine radical unit created after light-induced charge injection into the semiconductor; however, this did not translate to higher DSSC stability, which appears to be more sensitive to the basicity of the anchoring group for this series.
Cocrystal assembled by 1,4-diiodotetrafluorobenzene and phenothiazine based on C-I...pi/N/S halogen bond and other assisting interactions.[Pubmed:28362284]
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2017 Apr 1;73(Pt 2):210-216.
The halogen-bonded cocrystal of 1,4-diiodotetrafluorobenzene (1,4-DITFB) with the butterfly-shape non-planar heterocyclic compound Phenothiazine (PHT) was successfully assembled by the conventional solution-based method. X-ray single-crystal diffraction analysis reveals a 3:2 stoichiometric ratio for the cocrystal (1,4-DITFB/PHT), and the cocrystal structure is constructed via C-I...pi, C-I...N and C-I...S halogen bonds as well as other assisting interactions (e.g. C-H...F/S hydrogen bond, C-H...H-C and C-F...F-C bonds). The small shift of the 1,4-DITFB vibrational band to lower frequencies in FT-IR and Raman spectroscopies provide evidence to confirm the existence of the halogen bond. In addition, the non-planarity of the PHT molecule in the cocrystal results in PHT emitting weak phosphorescence and relatively strong delayed fluorescence. Thus, a wide range of delayed fluorescence and weak phosphorescence could play a significant role in selecting a proper pi-conjugated system to engineer functional cocrystal and luminescent materials by halogen bonds.
A comparative spectroscopic study of thiourea effect on the photophysical and molecular association behavior of various phenothiazine dyes.[Pubmed:28237658]
Spectrochim Acta A Mol Biomol Spectrosc. 2017 May 15;179:132-143.
This paper describes the role of a structure breaking additive (thiourea) on the photophysical and molecular association of a series of Phenothiazine dyes in aqueous media using the absorption and fluorescence spectroscopic methods for the first time. The studied dyes were thionine, azure A, azure B, toluidine blue, and methylene blue. The spectral data were analyzed using DECOM program. Relevant spectral parameters in the dye solutions were estimated and discussed based on the chemical structure of the additive and excitonic treatment. The observation of spectral changes in the spectral data of the (water-additive-dye) system indicates the possible structure formation between the dye and additive molecules. However, it is found that in the high concentrations of thiourea the dimer geometries (H- and J-type dimers) are influenced by the dye-additive interactions. As a result, a competition between the dye-additive and dye-dye interactions was also observed.
Comparative analysis of triarylamine and phenothiazine sensitizer donor units in dye-sensitized solar cells.[Pubmed:28165524]
Chem Commun (Camb). 2017 Feb 16;53(15):2367-2370.
A homologous set of dyes that differ only in the donor fragments, namely Phenothiazine (PTZ) and triarylamine (TPA) units, were evaluated in dye-sensitized solar cells (DSSCs). The novel PTZ-based dye differs from the TPA-based dye in that it contains a sulfur bridge that planarizes two aromatic rings and enables higher dye loading and higher stability in the oxidized form. These positive features notwithstanding, the superior absorptivity of devices sensitized by TPA-based dyes resulted in significantly higher power conversion efficiencies (PCEs) than those sensitized by PTZ-based dyes.
