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2-Ethylhexyl trans-4-methoxycinnamate

CAS# 83834-59-7

2-Ethylhexyl trans-4-methoxycinnamate

Catalog No. BCN1333----Order now to get a substantial discount!

Product Name & Size Price Stock
2-Ethylhexyl trans-4-methoxycinnamate:100mg $70.00 In stock
2-Ethylhexyl trans-4-methoxycinnamate:200mg $119.00 In stock
2-Ethylhexyl trans-4-methoxycinnamate:500mg $280.00 In stock
2-Ethylhexyl trans-4-methoxycinnamate:1000mg $490.00 In stock

Quality Control of 2-Ethylhexyl trans-4-methoxycinnamate

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Chemical structure

2-Ethylhexyl trans-4-methoxycinnamate

3D structure

Chemical Properties of 2-Ethylhexyl trans-4-methoxycinnamate

Cas No. 83834-59-7 SDF Download SDF
PubChem ID 5355130 Appearance Oil
Formula C18H26O3 M.Wt 290.4
Type of Compound Phenylpropanoids Storage Desiccate at -20°C
Solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Chemical Name 2-ethylhexyl (E)-3-(4-methoxyphenyl)prop-2-enoate
SMILES CCCCC(CC)COC(=O)C=CC1=CC=C(C=C1)OC
Standard InChIKey YBGZDTIWKVFICR-JLHYYAGUSA-N
General tips For obtaining a higher solubility , please warm the tube at 37 ℃ and shake it in the ultrasonic bath for a while.Stock solution can be stored below -20℃ for several months.
We recommend that you prepare and use the solution on the same day. However, if the test schedule requires, the stock solutions can be prepared in advance, and the stock solution must be sealed and stored below -20℃. In general, the stock solution can be kept for several months.
Before use, we recommend that you leave the vial at room temperature for at least an hour before opening it.
About Packaging 1. The packaging of the product may be reversed during transportation, cause the high purity compounds to adhere to the neck or cap of the vial.Take the vail out of its packaging and shake gently until the compounds fall to the bottom of the vial.
2. For liquid products, please centrifuge at 500xg to gather the liquid to the bottom of the vial.
3. Try to avoid loss or contamination during the experiment.
Shipping Condition Packaging according to customer requirements(5mg, 10mg, 20mg and more). Ship via FedEx, DHL, UPS, EMS or other couriers with RT, or blue ice upon request.

Source of 2-Ethylhexyl trans-4-methoxycinnamate

The barks of Cinnamomum cassia Presl

Biological Activity of 2-Ethylhexyl trans-4-methoxycinnamate

Description2-Ethylhexyl-p-methoxycinnamate is a sunscreen agent.
In vitro

Energy efficiency for the removal of non-polar pollutants during ultraviolet irradiation, visible light photocatalysis and ozonation of a wastewater effluent.[Pubmed: 23863371]

Water Res. 2013 Oct 1;47(15):5546-56.

This study aims to assess the removal of a set of non-polar pollutants in biologically treated wastewater using ozonation, ultraviolet (UV 254 nm low pressure mercury lamp) and visible light (Xe-arc lamp) irradiation as well as visible light photocatalysis using Ce-doped TiO2. The compounds tracked include UV filters, synthetic musks, herbicides, insecticides, antiseptics and polyaromatic hydrocarbons.
METHODS AND RESULTS:
Raw wastewater and treated samples were analyzed using stir-bar sorptive extraction coupled with comprehensive two-dimensional gas chromatography (SBSE-CG × GC-TOF-MS). Ozone treatment could remove most pollutants with a global efficiency of over 95% for 209 μM ozone dosage. UV irradiation reduced the total concentration of the sixteen pollutants tested by an average of 63% with high removal of the sunscreen 2-Ethylhexyl trans-4-methoxycinnamate (EHMC), the synthetic musk 7-acetyl-1,1,3,4,4,6-hexamethyltetrahydronaphthalene (tonalide, AHTN) and several herbicides. Visible light Ce-TiO2 photocatalysis reached ~70% overall removal with particularly high efficiency for synthetic musks. In terms of power usage efficiency expressed as nmol kJ(-1), the results showed that ozonation was by far the most efficient process, ten-fold over Xe/Ce-TiO2 visible light photocatalysis, the latter being in turn considerably more efficient than UV irradiation. In all cases the efficiency decreased along the treatments due to the lower reaction rate at lower pollutant concentration. The use of photocatalysis greatly improved the efficiency of visible light irradiation. The collector area per order decreased from 9.14 ± 5.11 m(2) m(-3) order(-1) for visible light irradiation to 0.16 ± 0.03 m(2) m(-3) order(-1) for Ce-TiO2 photocatalysis. The toxicity of treated wastewater was assessed using the green alga Pseudokirchneriella subcapitata.
CONCLUSIONS:
Ozonation reduced the toxicity of treated wastewater, while UV irradiation and visible light photocatalysis limited by 20-25% the algal growth due to the accumulation of reaction by-products. Three transformation products were identified and tracked along the treatments.

Protocol of 2-Ethylhexyl trans-4-methoxycinnamate

Structure Identification
J Pharm Biomed Anal. 2002 Nov 7;30(4):1181-9.

Comparative studies of the influence of cyclodextrins on the stability of the sunscreen agent, 2-ethylhexyl-p-methoxycinnamate.[Pubmed: 12408908]

The effects of beta-cyclodextrin (beta-CD) and hydroxypropyl-beta-cyclodextrin (HP-beta-CD) on the base-catalyzed degradation and light-induced decomposition of the sunscreen agent, trans-2-ethylhexyl-p-methoxycinnamate (2-Ethylhexyl trans-4-methoxycinnamate,trans-EHMC) were investigated.
METHODS AND RESULTS:
Reversed-phase liquid chromatography was used to study the interaction between natural and modified cyclodextrins, added to the mobile phase, and the sunscreen. Among the available cyclodextrins (beta-CD, HP-beta-CD, hydroxypropyl-alpha-cyclodextrin and hydroxypropyl-gamma-cyclodextrin), only HP-beta-CD and beta-CD produced a significant decrease in the chromatographic retention of trans-EHMC. The complexation of the sunscreen agent with HP-beta-CD and beta-CD was confirmed by thermal analysis and nuclear magnetic resonance spectroscopy. beta-CD depressed the decomposition of trans-EHMC in alkaline solutions more effectively than HP-beta-CD. Moreover, the irradiation-induced degradation of the sunscreen agent in emulsion vehicles was reduced by complexation with beta-CD (the extent of degradation was 26.1% for the complex compared to 35.8% for free trans-EHMC) whereas HP-beta-CD had no significant effect.
CONCLUSIONS:
Therefore, the complex of beta-CD with trans-EHMC enhances the chemical- and photo-stability of the sunscreen agent. Moreover, it limits adverse interactions of the UV filter with other formulation ingredients.

2-Ethylhexyl trans-4-methoxycinnamate Dilution Calculator

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2-Ethylhexyl trans-4-methoxycinnamate Molarity Calculator

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Preparing Stock Solutions of 2-Ethylhexyl trans-4-methoxycinnamate

1 mg 5 mg 10 mg 20 mg 25 mg
1 mM 3.4435 mL 17.2176 mL 34.4353 mL 68.8705 mL 86.0882 mL
5 mM 0.6887 mL 3.4435 mL 6.8871 mL 13.7741 mL 17.2176 mL
10 mM 0.3444 mL 1.7218 mL 3.4435 mL 6.8871 mL 8.6088 mL
50 mM 0.0689 mL 0.3444 mL 0.6887 mL 1.3774 mL 1.7218 mL
100 mM 0.0344 mL 0.1722 mL 0.3444 mL 0.6887 mL 0.8609 mL
* Note: If you are in the process of experiment, it's necessary to make the dilution ratios of the samples. The dilution data above is only for reference. Normally, it's can get a better solubility within lower of Concentrations.

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References on 2-Ethylhexyl trans-4-methoxycinnamate

Energy efficiency for the removal of non-polar pollutants during ultraviolet irradiation, visible light photocatalysis and ozonation of a wastewater effluent.[Pubmed:23863371]

Water Res. 2013 Oct 1;47(15):5546-56.

This study aims to assess the removal of a set of non-polar pollutants in biologically treated wastewater using ozonation, ultraviolet (UV 254 nm low pressure mercury lamp) and visible light (Xe-arc lamp) irradiation as well as visible light photocatalysis using Ce-doped TiO2. The compounds tracked include UV filters, synthetic musks, herbicides, insecticides, antiseptics and polyaromatic hydrocarbons. Raw wastewater and treated samples were analyzed using stir-bar sorptive extraction coupled with comprehensive two-dimensional gas chromatography (SBSE-CG x GC-TOF-MS). Ozone treatment could remove most pollutants with a global efficiency of over 95% for 209 muM ozone dosage. UV irradiation reduced the total concentration of the sixteen pollutants tested by an average of 63% with high removal of the sunscreen 2-Ethylhexyl trans-4-methoxycinnamate (EHMC), the synthetic musk 7-acetyl-1,1,3,4,4,6-hexamethyltetrahydronaphthalene (tonalide, AHTN) and several herbicides. Visible light Ce-TiO2 photocatalysis reached ~70% overall removal with particularly high efficiency for synthetic musks. In terms of power usage efficiency expressed as nmol kJ(-1), the results showed that ozonation was by far the most efficient process, ten-fold over Xe/Ce-TiO2 visible light photocatalysis, the latter being in turn considerably more efficient than UV irradiation. In all cases the efficiency decreased along the treatments due to the lower reaction rate at lower pollutant concentration. The use of photocatalysis greatly improved the efficiency of visible light irradiation. The collector area per order decreased from 9.14 +/- 5.11 m(2) m(-3) order(-1) for visible light irradiation to 0.16 +/- 0.03 m(2) m(-3) order(-1) for Ce-TiO2 photocatalysis. The toxicity of treated wastewater was assessed using the green alga Pseudokirchneriella subcapitata. Ozonation reduced the toxicity of treated wastewater, while UV irradiation and visible light photocatalysis limited by 20-25% the algal growth due to the accumulation of reaction by-products. Three transformation products were identified and tracked along the treatments.

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